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Place cocoa or morsels on a small plate. Place chocolate syrup on a separate small plate. Dip the rim of each martini glass into the syrup. Then run the rim gently through the cocoa/mini morsels. Place glasses in the refrigerator.
Fill a martini shaker halfway with ice. Add the chocolate liqueur, Crème de Cacao, vodka and evaporated milk. Cover the martini shaker and gently shake.
Pour the martinis into the prepared glasses. Serve immediately.